Acidez de los cationes metálicos

Acidez de los cationes metálicos

Objetivo

Determinar que factores influyen en un ion metálico para determinar su fuerza ácida

Antecedentes

Las teorías respecto a los ácidos y bases sonrealmente definiciones de los que es un ácido y una base, y las utilizamos de acuerdo a cual sea más conveniente para ser empleada en una situación particular.

Definición de Arrhenius

Define unácido como una sustancia que se ioniza en agua para producir iones H+ y a una base como una sustancia que se ioniza en agua para producir iones OH-.

Bronsted-Lowry

En forma independiente, en 1923,J.N. Bronsted y T.M. Lowry sugirieron que los ácidos se pueden definir como donadores y las bases como receptores de protones. En el caso de disoluciones acuosas la definición de Bronsted-Lowry nodifiere considerablemente de la de Arrhenius, de iones Hidrógeno (ácidos) y de iones hidróxido (bases)

Lewis.

De acuerdo con la definición de Lewis una base es una sustancia que puede donar un parde electrones y un ácido es una sustancia que puede aceptar un par de elctrones.

Análisis de resultados
Tabla 1
Catión pH pH
Li+ 5 14
Mg2+ 6 14
La3+ 4 6
Zr4+ 1 2

A los cationes más ácidosse les agregó NaOH 1M y a los menos ácidos NaOH 3M.

En la tabla 1 podemos observar que el catión más ácido fue el Zr4+ seguido del La3+, esto lo atribuimos a que son los que tienen mayor carga.Tabla 2
Catión pH pH con NaOH 1M
Li+ 5 14
Na+ 5 14
K+ 5 14
Ag+ 3 10

En la tabla 2 hay tres cationes que pertenecen a la familia 1 de metales alcalinos y uno que es un metal de transición.El catión Ag+ es más pequeño en comparación con Li+, Na+, o K+ y al tener todos la misma carga este es el factor determinante para saber el porque es el que presenta mayor carácter ácido, ya quepresenta una densidad alta de carga/tamaño: q 2/r .
El catión Ag+ fue el único que precipitó. No se observó precipitado con Li+, Na+ o K+, ya que éstos son muy solubles.

Tabla 3
Catión pH pH con…

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